While her dress was a stunner, Arquette immediately became one of Emmy's most memorable "Don'ts" with this overworked, unflattering vintage hairstyle. It bears repeating: when the gown is a masterpiece, keep the rest of the look simple.

Messing is a darling of the fashionista set, and moments like this are why. The amazing color of this gown set her entire look aglow. Super-shiny flowing hair, understated makeup and a bare neckline kept the look chic.

America Ferrera set herself far apart from her "Ugly Betty" character when she hit the red carpet in this amazing electric blue gown. The romantic updo hairstyle was the perfect companion with the sweetheart neckline of the dress. Understated makeup and a bare neckline, once again, kept the look chic.

Earlier in her career, Hargitay graced the Emmy red carpet in a stunning emerald green frock. Unfortunately, she also wore stunning green eye shadow and a huge yellow flower in her hair. The result would have been more at home at a luau.

If anyone thought Tina Fey really is Liz Lemon, they were quickly set straight when Fey accepted her Emmy in this incredibly chic deep purple gown. Again, the clean neckline, understated medium-length hair, and neutral makeup gave the dress the spotlight it deserved.