Anyone who was watching this night will always remember Aniston's dream of a gown, sexy tousled hair, and glowing skin. With a stunning showcase gown, it's best to keep the rest of the look simple.

This white gown was a breath of fresh air with its boatneck and open back. Huffman's delicate accessories kept the look clean and elegant. Neutral makeup and a simple updo were great choices, allowing the gown and choker to take center stage.

While her dress was a stunner, Arquette immediately became one of Emmy's most memorable "Don'ts" with this overworked, unflattering vintage hairstyle. It bears repeating: when the gown is a masterpiece, keep the rest of the look simple.

Messing is a darling of the fashionista set, and moments like this are why. The amazing color of this gown set her entire look aglow. Super-shiny flowing hair, understated makeup and a bare neckline kept the look chic.

America Ferrera set herself far apart from her "Ugly Betty" character when she hit the red carpet in this amazing electric blue gown. The romantic updo hairstyle was the perfect companion with the sweetheart neckline of the dress. Understated makeup and a bare neckline, once again, kept the look chic.